01Materials
Pick the material before the tolerance
Ceramics are not interchangeable, and the wrong choice cannot be machined back. Alumina for cost and insulation, zirconia for toughness, SiC for wear and thermal shock, AlN when heat has to leave — and machinable glass-ceramic when you need three prototypes this week.
Table 1 · Technical ceramic properties, typical values
| Material |
Density g/cm³ |
Hardness HV |
Flexural MPa |
KIC MPa·m½ |
CTE 10⁻⁶/K |
k W/m·K |
Max use °C, air |
| Alumina 99.5% Al₂O₃ |
3.90 |
1,600 |
360 |
4.0 |
7.2 |
30 |
1,650 |
| Alumina 96% cost grade |
3.70 |
1,600 |
300 |
3.5 |
6.5 |
25 |
1,600 |
| Zirconia 3Y-TZP ZrO₂ |
6.05 |
1,250 |
1,000 |
8.0 |
10.0 |
2.5 |
1,000 |
| ZTA alumina-toughened |
4.20 |
1,450 |
600 |
6.0 |
8.0 |
22 |
1,500 |
| Silicon nitride Si₃N₄ |
3.20 |
1,500 |
800 |
6.5 |
3.1 |
25 |
1,200 |
| Silicon carbide SSiC |
3.10 |
2,400 |
450 |
4.0 |
4.0 |
120 |
1,600 |
| Aluminium nitride AlN |
3.30 |
1,150 |
350 |
3.0 |
4.6 |
180 |
1,000 |
| Machinable glass-ceramic Macor-type |
2.52 |
250 |
100 |
1.5 |
9.3 |
1.6 |
800 |
Scroll the table sideways for all columns →
Why AlN is the exception. Its thermal conductivity is roughly six times alumina's — the reason it appears in LED bases, RF packages and heat spreaders. It is also brittle (KIC ~3) and expensive to grind, so it is specified only when the heat path is the problem.